HETEROBIMETALLIC 2-(DIMETHYLAMINOMETHYL)F ERROCENYL DERIVATIVES OF MONOVALENT GOLD

Authors
JACOB K VOIGT F MERZWEILER K WAGNER C ZANELLO P FONTANI M PIETZSCH C
Citation
K. Jacob et al., HETEROBIMETALLIC 2-(DIMETHYLAMINOMETHYL)F ERROCENYL DERIVATIVES OF MONOVALENT GOLD, Journal of organometallic chemistry, 552(1-2), 1998, pp. 265-276
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
552
Issue
1-2
Year of publication
1998
Pages
265 - 276
Database
ISI
SICI code
0022-328X(1998)552:1-2<265:H2EDOM>2.0.ZU;2-G
Abstract
[2-(dimethylaminomethyl)ferrocenyl]-lithium, FcNLi (I) reacts with gol d (I) complexes ClAu . L to heterobimetallic organo gold(I) compounds (FcN)Au . L [L = P(C6H3F2-m,p)(3) (1), P(C6H3F2-m,m)(3) (2), P(C6H4CH3 -o)(3) (3), P(C6H4CH3-m)(3) (4), P(C6H4CH3-p)(3) (5), P(C2H5)(3) (6)]. Starting from [FcNAu](2) and P(C6H4Cl-m)(3) the (FcN)Au . P(C6H4Cl-m) (3) (7) is formed. The organo gold derivatives 1-7 were characterized by mass-, NMR and Mossbauer spectroscopy as well as by cyclovoltammetr y and X-ray diffraction.