REACTIVITY OF METAL-CONTAINING MONOMERS - 48 - THERMAL TRANSFORMATIONS OF COBALT(II) MALEATE

Authors
ROSENBERG AS ALEKSANDROVA EI IVLEVA NP DZHARDIMALIEVA GI RAEVSKII AV KOLESOVA OI UFLYAND IE POMOGAILO AD
Citation
As. Rosenberg et al., REACTIVITY OF METAL-CONTAINING MONOMERS - 48 - THERMAL TRANSFORMATIONS OF COBALT(II) MALEATE, Russian chemical bulletin, 47(2), 1998, pp. 259-264
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
2
Year of publication
1998
Pages
259 - 264
Database
ISI
SICI code
1066-5285(1998)47:2<259:ROMM-4>2.0.ZU;2-L
Abstract
Thermal conversion of cobalt(II) maleate, CoC4H2O4 . 2H(2)O, (1) at 34 0-370 degrees C was studied. The composition of the products of pyroly sis was determined. The major solid-phase product of decomposition con sists of nano-sized particles of CoO (sizes vary within narrow limits) stabilized by the polymeric matrix. Thermal conversions of Co-II male ate involve dehydration, polymerization of dehydrated monomers, and de carboxylation of the resulting polymer.