(PH4P)(4)[PD7AS10S22] - A SULFOSALT WITH A LARGE CLUSTER ANION WHOSE STRUCTURE RESEMBLES A GONDOLA

Authors
HANKO JA CHOU JH KANATZIDIS MG
Citation
Ja. Hanko et al., (PH4P)(4)[PD7AS10S22] - A SULFOSALT WITH A LARGE CLUSTER ANION WHOSE STRUCTURE RESEMBLES A GONDOLA, Inorganic chemistry, 37(8), 1998, pp. 1670
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
8
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:8<1670:(-ASWA>2.0.ZU;2-O
Abstract
The [Pd(7)AS(10)S(22)](4-) molecule assembles under hydrothermal condi tions from Pd2+ and [AsS3](3-) to adopt the unusual shape of a gondola . Key to its formation appears to be the creation of direct Pd-As bond s.