ETHYLENE LIGAND STRUCTURES OF OS(CO)(4)(C2H4) AND OS-2(CO)(8)(C2H4) DETERMINED BY H-1-NMR IN LIQUID-CRYSTAL SOLVENTS

The ethylene complexes Os-2(CO)(8)(mu-eta(1),eta(1)-C2H4) (1) and Os(C O)(4)(eta-C2H4) (2) have been studied by H-1 NMR in liquid crystal (ne matic phase) solvents. For 1 or 2, three dipolar couplings were observ ed and assigned to intramolecular geminal, cis, and trans H-1-H-1 dipo lar couplings. The H-1 NMR spectrum of Os(CO)(4)((CH2CH2)-C-13)(2-C-13 ) has also been analyzed and two additional C-13-H-1 dipolar couplinps have allowed determination of the absolute bond angles and relative b ond lengths of the ethylene portion of 2 C-13. The observed dipolar co uplings for 2-C-13 have been corrected for harmonic vibrations. A comp arison of the ethylene geometry of 2 with that of other transition met al ethylene complexes and with free ethylene shows that the (C-2-H-4)O s unit of 2 is best described as a metallacyclopropane. Deuterium subs titution is used to demonstrate liquid crystal NMR as a stereochemical probe. The H-1 NMR spectrum of Os-2(CO)(8)(mu-eta(1),eta(1)-(CH2CH2)- C-13) (1-C-13) has also been analyzed in a nematic phase solvent. The dimetallacyclobutane ring of 1-C-13 is best described as two rapidly i nterconverting ring-puckered conformers of C-2-symmetry. The liquid cr ystal NMR derived structural parameters for 1-C-13 are compared with t hose previously determined by neutron diffraction. The solution and so lid-state structures are very similar. The ethylene complexes 1 and 2 are proposed as structural and spectroscopic models for ethylene chemi sorbed on metal surfaces.