SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF A CYCLIC DIMER OF YL-N-OXYLAMINO)-5-TERT-BUTYL-BENZENE)MANGANESE(II)

Authors
GORLITZ G HAYAMIZU T ITOH T MATSUDA K IWAMURA H
Citation
G. Gorlitz et al., SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF A CYCLIC DIMER OF YL-N-OXYLAMINO)-5-TERT-BUTYL-BENZENE)MANGANESE(II), Inorganic chemistry, 37(8), 1998, pp. 2083
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
8
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:8<2083:SSAMOA>2.0.ZU;2-5
Abstract
The cyclic dimer 1 was obtained by the reaction of the diradical -bis( N-tert-butyl-N-oxylamino)-5-tert-butylbenzene with Mn(hfac)(2). A spin transition occurs in 1 on cooling due to ferromagnetic coupling via t he bidentate diradical ligand. The temperature dependence of the magne tic properties can be interpreted quantitatively in the frame of the H DvV formalism.