Dk. Saha et al., STRUCTURAL-PROPERTIES OF DIAMOND FINE PARTICLES AND CLUSTERS PREPAREDBY DETONATION AND DECOMPOSITION OF TNT, Surface science, 400(1-3), 1998, pp. 134-139
The thermal parameter B for three different particle sizes of diamond
samples (bulk powder 1-4 mu m, fine particle 144-195 A and cluster 55-
61 Angstrom) was determined by the grazing incidence X-ray diffraction
method. The values of B were found to be in the ranee 0.50-0.70 Angst
rom(2) For particles in the size range 195-55 Angstrom and 0.27 Angstr
om(2) for 1-4 mu m. All of them are larger than that of diamond bulk.
A clear size dependence of B. increasing with decreasing particle size
, was found. By analysing X-ray diffraction data at several temperatur
es the magnitude of B was found to be due to B-S (static part) instead
of B-T (dynamic part). The average B, values obtained were 0.04 Angst
rom(2), 0.19 Angstrom(2) and 0.27 Angstrom(2) for bulk powder, fine pa
rticle and cluster samples respectively. Ultrahigh resolution transmis
sion electron microscope (TEM) observation confirmed the presence of s
train, distortion, roughness and dislocation lines in many particles.
TEM images of particles indicate that the clusters were not spherical
in shape: they were mostly cubiform and some were truncated prism-like
polyhedral. The present study reveals that the B,component is respons
ible for the large B value in diamond fine particles and clusters. No
clear surface local atomic distortion was found in the particles. (C)
1998 Elsevier Science B.V.