Soil moisture governs many biogeochemical processes in peatlands. Mode
ling of those processes relative to climate and anthropogenic influenc
es requires knowledge of the basic hydraulic properties of different p
eat soils in a function form. Water retention of undisturbed surface p
eat samples, collected at four depths at each of 38 undrained and drai
ned pine (Pinus sylvestris L.) mire sites, was measured for suction pr
essures of -0.98, -3.10, -6.19, -9.81, -98.1, and -1554.25 kPa, The ob
tained data were used to test several well-known water retention model
s commonly applied to mineral soils, The most suitable model was found
to be van Genuchten's model if the residual water content was omitted
. Feat characteristics were used to explain the variation in the model
's shape parameters. Accounting for the remains of Sphagnum, Carer, Er
iophorum, and lignin and the distinction between shallow and deep peat
layers considerably improved the moisture retention predictions compa
red with using bulk density only. The different behavior of the shallo
w vs. the deep peat layers was mainly attributed to the Sphagnum and l
ignin residues, but not to the Carer residues. We developed a semiempi
rical model with only one shape parameter, which was clearly better ex
plained by the peat characteristics than the two shape parameters of t
he van Genuchten model, We recommend that for statistical investigatio
ns or investigations requiring a robust model. the semiempirical model
be used. The van Genuchten model is to be preferred in predicting the
moisture conditions near saturation.