AN INDO S STUDY OF THE 2ND PI-PI-ASTERISK TRANSITION IN THE SPECTRA OF 1,4-DIAMINO ANTHRAQUINONES RESPONSIBLE FOR THEIR GREEN HUE/

Authors
YATSENKO AV TAFEENKO VA ZAKHAROV VN POPOV SI SCHENK H
Citation
Av. Yatsenko et al., AN INDO S STUDY OF THE 2ND PI-PI-ASTERISK TRANSITION IN THE SPECTRA OF 1,4-DIAMINO ANTHRAQUINONES RESPONSIBLE FOR THEIR GREEN HUE/, Dyes and pigments, 37(3), 1998, pp. 273-282
Citations number
30
Categorie Soggetti
Engineering, Chemical","Chemistry Applied","Materiales Science, Textiles
Journal title
Dyes and pigments → ACNP
ISSN journal
01437208
Volume
37
Issue
3
Year of publication
1998
Pages
273 - 282
Database
ISI
SICI code
0143-7208(1998)37:3<273:AISSOT>2.0.ZU;2-W
Abstract
The INDO/S approach is used to study the structure/spectra relationshi p for some N,N'-disubstituted 1,4-diaminoanthraquinones. The calculate d intensity and position of the short-wavelength absorption band depen d on the molecular conformation, in agreement with the experimental da ta. The reflection spectra of crystalline 1,4-bisanilinoanthraquinone and 1,4-bis(mesitylamino) anthraquinone are reported and the crystal s tructure of the latter compound has been determined. (C) 1998 Elsevier Science Ltd.