PALLADIUM-CATALYZED OXIDATIVE CYCLIZATION OF 1,4-DIOLS AND 1,5-DIOLS IN 1,2-DICHLOROETHANE

Citation
S. Aitmohand et J. Muzart, PALLADIUM-CATALYZED OXIDATIVE CYCLIZATION OF 1,4-DIOLS AND 1,5-DIOLS IN 1,2-DICHLOROETHANE, Journal of molecular catalysis. A, Chemical, 129(2-3), 1998, pp. 135-139
Citations number
22
Categorie Soggetti
Chemistry Physical
ISSN journal
13811169
Volume
129
Issue
2-3
Year of publication
1998
Pages
135 - 139
Database
ISI
SICI code
1381-1169(1998)129:2-3<135:POCO1A>2.0.ZU;2-3
Abstract
beta- and delta-lactones have been obtained from diols in 1,2-dichloro ethane containing sodium carbonate and catalytic amounts of both palla dium chloride and Adogen 464. In one case, the reaction stopped at the level of the lactol; a dealkoxypalladation is thus suggested. (C) 199 8 Elsevier Science B.V.