A RELATIONSHIP BETWEEN RAMAN AND INFRARED-SPECTRA - THE CASE OF PUSH-PULL MOLECULES

Authors
DELZOPPO M TOMMASINI M CASTIGLIONI C ZERBI G
Citation
M. Delzoppo et al., A RELATIONSHIP BETWEEN RAMAN AND INFRARED-SPECTRA - THE CASE OF PUSH-PULL MOLECULES, Chemical physics letters, 287(1-2), 1998, pp. 100-108
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
287
Issue
1-2
Year of publication
1998
Pages
100 - 108
Database
ISI
SICI code
0009-2614(1998)287:1-2<100:ARBRAI>2.0.ZU;2-U
Abstract
Vibrational spectra of push-pull polyenes show a peculiar feature name ly, in infrared and Raman spectra strong, coincident bands appear, ari sing from vibrations localised on the polyene bridge. A simple model, based on the introduction of an effective internal field due to the ch arge transfer between end groups allows the infrared and Raman intensi ties of these bands to be related. (C) 1998 Elsevier Science B.V. All rights reserved.