STABILITY OF GASEOUS FULLERENE CHLORIDES

Authors
DOROZHKO PA POPOV AA KOROBOV MV TUMANSKII BL
Citation
Pa. Dorozhko et al., STABILITY OF GASEOUS FULLERENE CHLORIDES, Chemical physics letters, 287(1-2), 1998, pp. 154-161
Citations number
13
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
287
Issue
1-2
Year of publication
1998
Pages
154 - 161
Database
ISI
SICI code
0009-2614(1998)287:1-2<154:SOGFC>2.0.ZU;2-F
Abstract
Individual gaseous species of fullerene chlorides have been successful ly generated in a molecular beam. Knudsen cell mass spectrometry has b een used to detect C60C2n (n = 0...9), C70C2m (m = 0...7) in the vapou r over the system C-60/C-70 (extract) with CrCl3 FeCl3 . 6H(2)O, FeCl3 (anhydrous) and CuCl2 (anhydrous) at temperatures from 520 to 720 K. Bond dissociation enthalpies for the fullerene chlorides have been est imated. (C) 1998 Elsevier Science B.V. All rights reserved.