COMPARISON OF INFRARED, RAMAN, PHOTOLUMINESCENCE, AND X-RAY PHOTOELECTRON-SPECTROSCOPY FOR CHARACTERIZING ARC-JET-DEPOSITED DIAMOND FILMS

Impurities and growth-related defect structures are mainly responsible for low thermal conductivity of chemical vapor deposited diamond film s. Different quality are-jet-deposited, free-standing diamond samples were obtained from industry. Fourier transform infrared (FTIR), Raman, and x-ray photoelectron spectroscopy (XPS) were used to determine the quality of these samples. The nondiamond carbon was estimated from th e 1560 cm(-1) broad peak intensity, the CHx integrated peak absorbance , and the C-1s, plasmon loss features for Raman, FTIR, and XPS studies , respectively. The diamond quality was also determined from the Raman diamond peak full width at half maximum (FWHM) and XPS valence band s pectra. It was observed that the higher the hydrogen content (determin ed by FTIR), the darker the color of the film, the larger the nondiamo nd 1560 cm(-1) peak intensity, and the larger the FWHM of the Raman di amond peak at 1332 cm(-1) Negligible difference in the C-1s, diamond b ulk plasmon loss peak was observed for films of wide ranging quality. The FTIR CHx band exhibited the highest sensitivity to film quality. I mpurity-related peaks were observed in the one phonon region of the FT IR spectra and the photoluminescence spectra. The photoluminescence ba ckground peak centered at 2.0 eV was found to be strongly related to n ondiamond carbon impurities. It is shown that a combination of differe nt analytical tools is required to determine diamond quality. (C) 1998 American Institute of Physics.