ADSORPTION OF DIMERIZING AND DIMER FLUIDS IN DISORDERED POROUS-MEDIA

The pair distribution functions and the adsorption isotherms for a har d-core dimerizing fluid in disordered hard-sphere matrices have been d etermined using the associative extension of replica Ornstein-Zernike equations. Some grand canonical Monte Carlo simulation results for tan gent hard-sphere dumbbells adsorbed in hard-sphere matrices are presen ted. Theoretical predictions for the structure from the solutions of i ntegral equations with the associative hypernetted chain (HNC) and Per cus-Yevick (PY) approximation agree with those from the simulations. H owever, the HNC closure has been found to work better than the PY one.