The thermalization of positronium (Ps) formed at a few eV in gases is
investigated using time-resolved, Doppler broadening measurements of t
he annihilation photons. Magnetic quenching permits energy measurement
s about 40 ns after Ps is formed in H-2, N-2, He, Ne, Ar, isobutane, a
nd neopentane. The thermalization rate is measured by changing the gas
density, and a classical elastic scattering cross section and a Ps fo
rmation energy are determined. The impact of Ps thermalization on deca
y rate experiments using gases is also discussed.