STABILIZATION OF EMULSION POLYMERIZATION BY BLOCK AND GRAFT-COPOLYMERS WITH POLYSILOXANE AND POLY[(ACETYLIMINO)ETHYLENE] SEQUENCES

Authors
SIMIONESCU CI DAVID G ALUPEI V RUSA M IOANID A SIMIONESCU BC
Citation
Ci. Simionescu et al., STABILIZATION OF EMULSION POLYMERIZATION BY BLOCK AND GRAFT-COPOLYMERS WITH POLYSILOXANE AND POLY[(ACETYLIMINO)ETHYLENE] SEQUENCES, Die Angewandte makromolekulare Chemie, 255, 1998, pp. 17-21
Citations number
16
Categorie Soggetti
Polymer Sciences
Journal title
Die Angewandte makromolekulare Chemie → ACNP
ISSN journal
00033146
Volume
255
Year of publication
1998
Pages
17 - 21
Database
ISI
SICI code
0003-3146(1998)255:<17:SOEPBB>2.0.ZU;2-I
Abstract
Amphiphilic block and graft copolymers with polysiloxane and poly[(ace tylimino)ethylene] sequences were used as nonionic surfactants in the emulsion polymerization of some vinyl monomers (styrene, methyl methac rylate, butyl methacrylate). The peculiarities of the systems (polymer ization kinetics and emulsion characteristics) were related to the str uctural features of the studied emulsifiers and suggested their abilit y to participate in initiation and transfer reactions and respectively clouding phenomena in aqueous phase.