The waste clay produced from refining waste lubricating oil contains a
bout 30% oil. Laboratory research has been carried out on the selectiv
e separation of oil by flotation using linear barium alkyl benzene sul
fonates as a collector. The behaviour of this collector at the solutio
n-air interface is studied; the critical micelle concentration (CMC),
efficiency (II), and effectiveness (P-C30) of the collector are determ
ined. The effects of collector concentration and addition mode are inv
estigated. The liquid-vapour interfacial tension was controlled by met
hanol. The selectivity achieved by the use of methanol is explained in
terms of critical surface tension of floatability and CMC. In additio
n the physico-chemical characteristics of the recovered oil at optimum
conditions are determined.