SOLVATOCHROMIC LINEAR SOLVATION ENERGY RELATIONSHIPS FOR SOLUBILITY OF O-2 IN VARIOUS SOLVENTS

Authors
CHE Y TOKUDA K OHSAKA T
Citation
Y. Che et al., SOLVATOCHROMIC LINEAR SOLVATION ENERGY RELATIONSHIPS FOR SOLUBILITY OF O-2 IN VARIOUS SOLVENTS, Bulletin of the Chemical Society of Japan, 71(3), 1998, pp. 651-656
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
71
Issue
3
Year of publication
1998
Pages
651 - 656
Database
ISI
SICI code
0009-2673(1998)71:3<651:SLSERF>2.0.ZU;2-V
Abstract
Linear solvation energy relationships for solution of O-2 in 27 solven ts have been examined. Multiple linear regression equations for mole f raction solubility of O-2 are developed based on Hildebrand's solubili ty parameter delta(H)(2) as well as the pi, alpha and beta solvatochr omic parameters describing the solvent polarizability/dipolarity, hydr ogen bond acidity and hydrogen bond basicity, respectively. Use of the combination of these parameters enables the medium effect on solution of O-2 to be correlated and interpreted in a conceptually simple mann er.