IR MULTIPLE-PHOTON DISSOCIATION OF BR(CF2)(4)COI MOLECULES BY EXCITATION VIA C=O (1794 CM(-1)) STRETCHING AND SKELETON (961 CM(-1)) VIBRATIONS

Authors
DEMYANENKO AV RYABOV EA LETOKHOV VS
Citation
Av. Demyanenko et al., IR MULTIPLE-PHOTON DISSOCIATION OF BR(CF2)(4)COI MOLECULES BY EXCITATION VIA C=O (1794 CM(-1)) STRETCHING AND SKELETON (961 CM(-1)) VIBRATIONS, Chemical physics letters, 286(3-4), 1998, pp. 277-283
Citations number
19
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
286
Issue
3-4
Year of publication
1998
Pages
277 - 283
Database
ISI
SICI code
0009-2614(1998)286:3-4<277:IMDOBM>2.0.ZU;2-#
Abstract
Dissociation of Br(CF2)(4)COI molecules resulting from infrared multip le-photon excitation (IR-MPE) by the second (via C=O stretch) and the first (via skeleton vibrations) harmonics of TEA CO2 laser was studied . It was found that in the two cases of IR-MPE, dissociation occurs vi a two distinct channels with the formation of C2F4 and Br(CF2)(4)I mol ecules as final products. At the same time, the relative ratio of thes e final products was found to depend on the channel of molecular excit ation. (C) 1998 Elsevier Science B.V.