C. Herzberg et Jz. Zhang, MELTING EXPERIMENTS IN THE SYSTEMS CAO-MGO-AL2O3-SIO2 AND MGO-SIO2 AT3 TO 15 GPA, The American mineralogist, 83(5-6), 1998, pp. 491-500
The results of multi-anvil melting experiments are reported for a rang
e of compositions in the system CaO-MgO-Al2O3-SiO2. The liquidus cryst
allization fields for forsterite, orthopyroxene, clinopyroxene, and ga
rnet have been mapped out at 10 GPa, as have their intersections at va
rious cotectics. The composition of the liquid that is multiply satura
ted in forsterite, orthopyroxene, clinopyroxene, and garnet has been a
lso determined to within +/-0.5-1.0 wt% (2 sigma), and the result is i
n excellent agreement with a previous estimate (Herzberg 1992). These
experiments confirm that the effect of pressure is to reduce Al2O3 and
increase MgO and SiO2 in magmas formed by the melting of garnet Iherz
olite with increasing pressure (Herzberg 1992). Melting experiments in
the system MgO-SiO2 also have been performed to constrain how pressur
e affects the compositions of liquids that are saturated in harzburgit
e [L + Ol + Opx]. Experiments in both CaO-MgO-Al2O3-SiO2 and MgO-SiO,
demonstrate that there is a maximum normative olivine content to liqui
ds formed by initial or advanced melting of peridotite in the upper ma
ntle, and this occurs at 7 to 8 GPa. For most peridotites that undergo
decompression melting in a plume, clinopyroxene and garnet are the fi
rst crystalline phases to melt out and, with a few important but rare
exceptions, the experimentally constrained liquids are unlike most vol
canic rocks. Advanced anhydrous melting will yield liquids with a resi
dual harzburgite mineralogy [L + Ol + Opx], and these liquids are simi
lar in composition to most komatiites with Cretaceous and 2700 Myr Arc
haean ages.