Jh. Choy et al., INTRA-LAYER AND INTER-LAYER STRUCTURES OF LAYERED HYDROXY DOUBLE SALTS, NI1-XZN2X(OH)(2)(CH3CO2)(2X)CENTER-DOT-NH(2)O, Materials letters, 34(3-6), 1998, pp. 356-363
Layered nickel and zinc hydroxy double acetates have been prepared by
both hydrothermal and coprecipitation methods. According to the X-ray
absorption spectroscopic analyses at the Ni and Zn K-edge for the hydr
othermally prepared precipitates, it was found that the brucite-type n
ickel hydroxide is formed with partial nickel vacancies, and the zinc
ions are stabilized in tetrahedral sites just below and above the nick
el vacant sites in hydroxide planes, with three hydroxide and one acet
ate ligands. The X-ray diffraction patterns indicate that the hydrothe
rmally prepared precipitates exhibit an evolution of the interlayer di
stance with respect to air-drying time at 25 degrees C, while such a c
hange could not be observed for precipitates obtained by coprecipitati
on. Such a different behavior arises from the difference in their posi
tive layer charges and the contents of inserted acetate anion. From th
e FT-IR spectroscopic study, it is concluded that the reversible struc
tural phase transformation is resulting from the change of orientation
of intercalated acetates depending on the type of ligation, chelating
or unidentate ones. (C) 1998 Elsevier Science B.V.