ON THE ORIGIN OF 1,5-INDUCTION IN TIN(IV) HALIDE-PROMOTED REACTIONS OF 4-ALKOXYALK-2-ENYLSTANNANES WITH ALDEHYDES

Authors
HOBSON LA VINCENT MA THOMAS EJ HILLIER IH
Citation
La. Hobson et al., ON THE ORIGIN OF 1,5-INDUCTION IN TIN(IV) HALIDE-PROMOTED REACTIONS OF 4-ALKOXYALK-2-ENYLSTANNANES WITH ALDEHYDES, Chemical communications, (8), 1998, pp. 899-900
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
8
Year of publication
1998
Pages
899 - 900
Database
ISI
SICI code
1359-7345(1998):8<899:OTOO1I>2.0.ZU;2-E
Abstract
A combination of experiment and theory has identified both the allylti n trichlorides 3 (R-2 = Bn, H) as key intermediates in tin(rv) chlorid e-promoted reactions of allylstannanes 1 (R-2 = Bn, H) and the transit ion structures that are involved in their reactions with aldehydes.