NEW CLUSTER CONDENSATION MODES IN EARLY TRANSITION-METAL THIOPHOSPHATES - SYNTHESIS, STRUCTURE AND PROPERTIES OF CSTA4P3S19, A NOVEL LAYERED MATERIAL

Authors
DERSTROFF V TREMEL W
Citation
V. Derstroff et W. Tremel, NEW CLUSTER CONDENSATION MODES IN EARLY TRANSITION-METAL THIOPHOSPHATES - SYNTHESIS, STRUCTURE AND PROPERTIES OF CSTA4P3S19, A NOVEL LAYERED MATERIAL, Chemical communications, (8), 1998, pp. 913-914
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
8
Year of publication
1998
Pages
913 - 914
Database
ISI
SICI code
1359-7345(1998):8<913:NCCMIE>2.0.ZU;2-Y
Abstract
The new layer compound CsTa4S5(S-2)(PS4)(3) was synthesized by the rea ction of Ta metal in polythiophosphate melts. Its structure is based o n Ta4S5(S-2) clusters which are condensed by PS43- groups.