CIS-2-AMINO-1-ACENAPHTHENOL - PRACTICAL RESOLUTION AND APPLICATION TOTHE CATALYTIC ENANTIOSELECTIVE REDUCTION OF KETONES

Authors
SUDO A MATSUMOTO M HASHIMOTO Y SAIGO K
Citation
A. Sudo et al., CIS-2-AMINO-1-ACENAPHTHENOL - PRACTICAL RESOLUTION AND APPLICATION TOTHE CATALYTIC ENANTIOSELECTIVE REDUCTION OF KETONES, Tetrahedron : asymmetry, 6(8), 1995, pp. 1853-1856
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
8
Year of publication
1995
Pages
1853 - 1856
Database
ISI
SICI code
0957-4166(1995)6:8<1853:C-PRAA>2.0.ZU;2-Q
Abstract
The chiral amino alcohol, cis-2-amino-1-acenaphethenol, was resolved v ia its (R)-2-phenylpropionic acid salt. This amino alcohol was used as the precursor of a chiral oxazaborolidine, which was an efficient chi ral catalyst in the asymmetric reduction of prochiral ketones.