MOVABLE REDUCTION BED HYDRIDE GENERATOR COUPLED WITH INDUCTIVELY-COUPLED PLASMA OPTICAL-EMISSION SPECTROMETRY FOR THE DETERMINATION OF SOMEHYDRIDE FORMING ELEMENTS

Authors
TIAN XD ZHUANG ZX CHEN B WANG XR
Citation
Xd. Tian et al., MOVABLE REDUCTION BED HYDRIDE GENERATOR COUPLED WITH INDUCTIVELY-COUPLED PLASMA OPTICAL-EMISSION SPECTROMETRY FOR THE DETERMINATION OF SOMEHYDRIDE FORMING ELEMENTS, Analyst, 123(4), 1998, pp. 627-632
Citations number
39
Categorie Soggetti
Chemistry Analytical
Journal title
Analyst → ACNP
ISSN journal
00032654
Volume
123
Issue
4
Year of publication
1998
Pages
627 - 632
Database
ISI
SICI code
0003-2654(1998)123:4<627:MRBHGC>2.0.ZU;2-Q
Abstract
A new hydride generation system, 'movable reduction bed hydride genera tor' has been developed which accomplishes hydride generation at micro liter sample volume without the need for an external addition of acid, or the use of a gas-liquid separator. Interferences among hydride for ming elements have been greatly reduced. The technique may offer a pos sibility for automatic operation, and could be used as an interface fo r LC, CE and other chromatographic techniques. The recoveries of As, S e and Sb by standard addition from a Chinese tea are 81.1(+/-2.7%), 10 2.6 (+/-3.4%) and 94.1% (+/-4.1%), respectively.