P-TOLUENESULFONYL ESTERS OF PERFLUORINATED TERTIARY ALCOHOLS - CRYSTAL-STRUCTURE DETERMINATION OF THE ABSOLUTE-CONFIGURATION OF C6F5(CF3)(2)COSO2C6H4CH3

Authors
KRUMM B VIJ A KIRCHMEIER RL SHREEVE JM
Citation
B. Krumm et al., P-TOLUENESULFONYL ESTERS OF PERFLUORINATED TERTIARY ALCOHOLS - CRYSTAL-STRUCTURE DETERMINATION OF THE ABSOLUTE-CONFIGURATION OF C6F5(CF3)(2)COSO2C6H4CH3, Journal of fluorine chemistry, 89(1), 1998, pp. 19-22
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
89
Issue
1
Year of publication
1998
Pages
19 - 22
Database
ISI
SICI code
0022-1139(1998)89:1<19:PEOPTA>2.0.ZU;2-W
Abstract
Selected perfluorinated tertiary alcohols can be reacted with p-toluen esulfonyl chloride to form their p-toluenesulfonyl esters C6F5(CF3)(2) COSO2C6H4CH3 (1), CF3C6F4OC6F4(C3F7)(C8F17)COSO2C6H4CH3 (2) and (CF3C6 F4OC6F4)(2)(C7F15)COSO2C6H4CH3 (3). The absolute configuration of 1 is established by X-ray diffraction. (C) 1998 Elsevier Science S.A. All rights reserved.