PALLADIUM-MEDIATED ENANTIOSELECTIVE FORMATION OF 2-METHYLTETRAL-1-ONEFROM THE CORRESPONDING ALLYL OR BENZYL ENOL CARBONATE IN THE PRESENCEOF ENANTIOPURE AMINOALCOHOLS

Authors
ABOULHODA SJ LETINOIS S WILKEN J REINERS I HENIN F MARTENS J MUZART J
Citation
Sj. Aboulhoda et al., PALLADIUM-MEDIATED ENANTIOSELECTIVE FORMATION OF 2-METHYLTETRAL-1-ONEFROM THE CORRESPONDING ALLYL OR BENZYL ENOL CARBONATE IN THE PRESENCEOF ENANTIOPURE AMINOALCOHOLS, Tetrahedron : asymmetry, 6(8), 1995, pp. 1865-1868
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
8
Year of publication
1995
Pages
1865 - 1868
Database
ISI
SICI code
0957-4166(1995)6:8<1865:PEFO2>2.0.ZU;2-V
Abstract
The palladium-induced cleavage at room temperature of (2-methyl-1-tetr alenyl) benzyl carbonate under bubbling of hydrogen led to (R) 2-methy ltetral-1-one with 90% chemical yield and 64% enantiomeric excess in t he presence of catalytic amounts of (+) endo-2-hydroxy-endo-3-aminobor nane.