Cu K-edge Extended X-ray Absorption Fine Structure (EXAFS) measurement
s have been made to understand the local structure of superconducting
La2CuO4.1 single crystal. The temperature dependent correlated Debye-W
aller factors of Cu-O(planar) and Cu-La pairs show anomalous behavior
at similar to 170 K. This temperature has been assigned to the orderin
g of CuO6 octahedral tiltings. The results show an interplay between t
he structural modulation of the perovskite and rock-salt layers in the
title compound. (C) 1998 Elsevier Science B.V.