ASYMMETRIC HYDROFORMYLATION OF STYRENE USING DITHIOLATO BRIDGED DIRHODIUM CATALYST WITH BDPP AS CHIRAL LIGAND

Authors
MASDEUBULTO AM OREJON A CASTILLON S CLAVER C
Citation
Am. Masdeubulto et al., ASYMMETRIC HYDROFORMYLATION OF STYRENE USING DITHIOLATO BRIDGED DIRHODIUM CATALYST WITH BDPP AS CHIRAL LIGAND, Tetrahedron : asymmetry, 6(8), 1995, pp. 1885-1888
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
8
Year of publication
1995
Pages
1885 - 1888
Database
ISI
SICI code
0957-4166(1995)6:8<1885:AHOSUD>2.0.ZU;2-6
Abstract
Asymmetric hydroformylation of styrene is performed using dinuclear th iolato bridged rhodium complexes with BDPP as the chiral auxiliary lig and. The optical yields observed depend on the starting organometallic complex. When (+) and (-) dithiolate bridged complexes and (+) and (- ) diphosphine are combined there is one pair which enhances the enanti oselectivity.