T. Sekine et al., SPIN-PEIERLS GAP AND 2-MAGNETIC-EXCITATION BOUND AND RESONANT STATES IN CU1-XZNXGEO3 AND CUGE1-YSIYO3, Journal of the Physical Society of Japan, 67(4), 1998, pp. 1440-1450
We study a spin-Peierls gap and a bound and a resonant states of two m
agnetic excitations in Cu1-xZnxGeO3 and CuGe1-ySiyO3. Breakdown of the
selection rule in the doped samples enables us to observe the spin-Pe
ierls gap excitation in the first-order Raman process. It is found tha
t this excitation shifts to lower frequency and merges into the tail o
f the elastic scattering together with its line broadening with increa
sing dopant concentration. The bound state of a particle-hole pair is
observed just below the bottom of the second-order Raman band in pure
CuGeO3. It changes into a resonant state and disappears rapidly as the
concentration of the dopant is increased, owing to the weakening of a
ttractive interaction and the extreme increase of the dampings of the
magnetic excitations. These features are demonstrated theoretically by
using Green's function.