DIRECT CHROMATOGRAPHIC RESOLUTION OF P-CHIRAL PHOSPHINOYLETHENES ON ACHIRAL STATIONARY-PHASE CONTAINING -(3,5-DINITROBENZOYL)-TRANS-1,2-DIAMINOCYCLOHEXANE AS SELECTOR

Authors
BRANDI A CICCHI S GASPARRINI F MAGGIO F VILLANI C KOPROWSKI M PIETRUSIEWICZ KM
Citation
A. Brandi et al., DIRECT CHROMATOGRAPHIC RESOLUTION OF P-CHIRAL PHOSPHINOYLETHENES ON ACHIRAL STATIONARY-PHASE CONTAINING -(3,5-DINITROBENZOYL)-TRANS-1,2-DIAMINOCYCLOHEXANE AS SELECTOR, Tetrahedron : asymmetry, 6(8), 1995, pp. 2017-2022
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
8
Year of publication
1995
Pages
2017 - 2022
Database
ISI
SICI code
0957-4166(1995)6:8<2017:DCROPP>2.0.ZU;2-K
Abstract
A pi-acidic, totally synthetic HPLC chiral stationary phase is used to separate the enantiomers of a wide range of unsaturated P-chiral phos phine oxides. If allows for fast, sensitive and accurate e.e. determin ations and secures easy access to opfically pure enantiomers by chroma tography on preparative columns.