Md. Guillen et Ml. Ibargoitia, NEW COMPONENTS WITH POTENTIAL ANTIOXIDANT AND ORGANOLEPTIC PROPERTIES, DETECTED FOR THE FIRST TIME IN LIQUID SMOKE FLAVORING PREPARATIONS, Journal of agricultural and food chemistry, 46(4), 1998, pp. 1276-1285
A commercial aqueous smoke preparation was exhaustively extracted, usi
ng dichioromethane as solvent, until the carrier had totally lost its
smoky odor. Qualitative and quantitative characterizations of the extr
act mere performed by means of gas chromatography/mass spectrometry an
d gas chromatography with flame ionization detector, respectively. Car
bonyl derivatives including aldehydes and ketones as well as acids and
esters are almost absent; however, the high proportion of phenol, gua
iacol, and syringol derivatives is noticeable. The presence of di-tert
-butylhydroxytoluene, several hopanes, and a number of Lignin dimers m
ust be pointed out; these latter components had apparently not been de
tected before either in smoke flavorings or in wood smoke. The mass sp
ectral data of the compounds considered as lignin dimers and of the un
identified components are given. The presence of Lignin dimers is very
interesting from the point of view of health and food technology for
their therapeutic, organoleptic, and antioxidant properties.