Rd. Marshall et al., OPTIMIZING CONTROL OF MICROWAVE PLASMA BIAS ENHANCED NUCLEATION FOR HETEROEPITAXIAL CHEMICAL-VAPOR-DEPOSITION DIAMOND, DIAMOND AND RELATED MATERIALS, 6(5-7), 1997, pp. 676-680
Bias enhanced nucleation (BEN) during microwave plasma enhanced chemic
al vapour deposition of diamond on Si(100) has been studied using atom
ic force microscopy (AFM), scanning electron microscopy, Raman scatter
ing and optical reflectivity measurements. The critical nature of the
BEN treatment period in the formation of nuclei that subsequently lead
to high quality oriented films has been demonstrated. An effective te
chnique is described for determining when optimal BEN treatment has be
en carried out on Si substrates which should be independent of the rea
ctor in use. (C) 1997 Elsevier Science S.A.