E. Dejean et al., WATER DEMINERALIZATION BY ELECTRODEIONIZATION WITH ION-EXCHANGE TEXTILES - COMPARISON WITH CONVENTIONAL ELECTRODIALYSIS, Separation science and technology, 33(6), 1998, pp. 801-818
An electrodeionization process has been developed using ion-exchange t
extiles (EDIT) instead of ion-exchange resins as currently used for th
e production of ultrapure water. The study was carried out with a labo
ratory pilot. Each membrane had an active area of 20 cm(2). Experiment
s were performed with NaCl solutions at low concentration (from 3 to 3
00 mg.L-1) under various experimental conditions of flow rate and curr
ent density. Different configurations of textile were tested: the dilu
ate compartment of the electrodialysis stack was filled by either alte
rnating layers of cation or anion-exchange textiles, or one layer of a
mphoteric textile or bipolar textile. The best results were obtained w
ith the latter configuration. The study allowed comparison of the perf
ormances of EDIT with conventional electrodialysis (ED) in terms of cu
rrent efficiency, demineralization ratio, and energy losses. A signifi
cant improvement was obtained by introducing the textile. At the lowes
t concentration (3 mg.L-1) and the highest flow rate (20.8 cm.s(-1)),
the current and demineralization efficiencies were 150% higher with ED
IT than with ED.