Tm. Grehk et al., RESONANT L-3-M4,5N4,5 AUGER-ELECTRON SPECTROSCOPY AS A PROBE FOR THE LOCAL ELECTRONIC-STRUCTURE IN PDXAG1-X ALLOYS, Journal of electron spectroscopy and related phenomena, 88, 1998, pp. 241-245
The Pd L-3-M4,5N4,5 Auger spectra from the pure metal and several PdxA
g1-x alloys were studied for sub-threshold excitation energies utilisi
ng the resonant line narrowing. Upon alloying, a characteristic line b
roadening with decreasing palladium concentration is observed. The mea
sured energy shifts in the Auger parameter are in agreement with an in
crease in the local d-charge density at the palladium sites in the Pdx
Ag1-x alloys. (C) 1998 Elsevier Science B.V.