The feasibility of using reactive coating of dolomite to obtain an ori
ented CaAl12O19 (hibonite) coating on alumina substrates has been show
n. The textured hibonite grains grow oriented along the [110] directio
n on the alumina substrate. By using single crystal of sapphire it has
been proved that the orientation of the hibonite layer is Mot depende
nt upon the crystal orientation of the alumina substrate. Alumina-alum
ina sandwiches with a weak interface have been prepared using this rea
ctive coating technique. (C) 1997 Elsevier Science Limited.