ELECTROSYNTHESIS OF NEW FUNCTIONALIZED DIFLUORO ALLYLSILANES

Authors
RAJAONAH M ROCK MH BEGUE JP BONNETDELPON D CONDON S NEDELEC JY
Citation
M. Rajaonah et al., ELECTROSYNTHESIS OF NEW FUNCTIONALIZED DIFLUORO ALLYLSILANES, Tetrahedron letters, 39(20), 1998, pp. 3137-3140
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
20
Year of publication
1998
Pages
3137 - 3140
Database
ISI
SICI code
0040-4039(1998)39:20<3137:EONFDA>2.0.ZU;2-L
Abstract
An efficient electrochemical silylation of chlorodifluoromethyl enol e thers 2 afforded in good yields the new functionalized difluoromethyl allylsilanes 1 on a preparative scale. These silanes reacted as difluo romethyl anion equivalents with an aldehyde as electrophile, providing functionalized a-difluoromethyl alcohols 4. (C) 1998 Published by Els evier Science Ltd. All rights reserved.