NITROSOCARBONYL INTERMEDIATES AS SUPER-ENOPHILES - A MILD METHOD FOR CARBON-NITROGEN BOND FORMATION

Authors
QUADRELLI P MELLA M CARAMELLA P
Citation
P. Quadrelli et al., NITROSOCARBONYL INTERMEDIATES AS SUPER-ENOPHILES - A MILD METHOD FOR CARBON-NITROGEN BOND FORMATION, Tetrahedron letters, 39(20), 1998, pp. 3233-3236
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
20
Year of publication
1998
Pages
3233 - 3236
Database
ISI
SICI code
0040-4039(1998)39:20<3233:NIAS-A>2.0.ZU;2-L
Abstract
Nitrosocarbonyl intermediates, generated at r.t. by the mild oxidation of nitrile oxides, undergo clean ene reactions with tetramethyl-and t rimethyl-ethylene and with cyclohexene. With less substituted ethylene s the ene pathway is still active but the oxidation step of the nitril e oxides competes with the cycloadditions to the olefins. (C) 1998 Els evier Science Ltd. All rights reserved.