INTERMOLECULAR HECK-DIELS-ALDER CASCADE PROCESSES OF ALKYLALLENES

Authors
GRIGG R BROWN S SRIDHARAN V UTTLEY MD
Citation
R. Grigg et al., INTERMOLECULAR HECK-DIELS-ALDER CASCADE PROCESSES OF ALKYLALLENES, Tetrahedron letters, 39(20), 1998, pp. 3247-3250
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
20
Year of publication
1998
Pages
3247 - 3250
Database
ISI
SICI code
0040-4039(1998)39:20<3247:IHCPOA>2.0.ZU;2-4
Abstract
Intermolecular Heck reaction of a wide variety of aryl/heteroaryl iodi des with alkylallenes Furnishes 1,3-dienes which undergo in situ Diels -Alder cycloaddition to N-methylmaleimide. This cascade can be further extended by interfacing with a prior Pd catalysed cyclisation. (C) 19 98 Elsevier Science Ltd. All rights reserved.