A NEW-TYPE OF S-S DICATION - PREPARATION AND REACTIONS WITH ALKENES AND DIENES

Authors
NENAJDENKO VG SHEVCHENKO NE BALENKOVA ES
Citation
Vg. Nenajdenko et al., A NEW-TYPE OF S-S DICATION - PREPARATION AND REACTIONS WITH ALKENES AND DIENES, Tetrahedron, 54(20), 1998, pp. 5353-5362
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
20
Year of publication
1998
Pages
5353 - 5362
Database
ISI
SICI code
0040-4020(1998)54:20<5353:ANOSD->2.0.ZU;2-M
Abstract
The reaction of dimethyl sulfide ditriflate with dimethyl sulfide lead s to the formation of tetramethyldisulfonium ditriflate 1a representin g a first example of acyclic S-S dication. Similarly was prepared S-S dication 1b from tetrahydrothiophene. It was found that dications 1a a nd 1b react with arylalkenes. The reaction forms the corresponding 1,2 -disulfonium salts. Conjugated dienes afford 1,4-disulfonium salts. (C ) 1998 Elsevier Science Ltd. All rights reserved.