T. Osaka et al., STRUCTURAL DEFECTS IN SR0.7BI2.3TA2O9 THIN-FILM FOR FERROELECTRIC MEMORY, IEICE transactions on electronics, E81C(4), 1998, pp. 545-551
Using transmission electron microscopy (TEM), we studied structural de
fects in a Sr0.7Bi2.3Ta2O9 (SBT) thin film to be used for ferroelectri
c memory devices. We examined the effects of the substrate, crystal co
ntinuity, and dislocations in crystals as major causes of defects. For
this study, we used an SBT thin film grown From an alkoxide solution.
Since crystal growth was hardly influenced by the substrate, the subs
trate had little influence on the occurrence of defects resulted in mi
sfit of lattice constant. Regions of partially low crystal continuity
were observed in the SBT thin film. In these regions, the orientation
was still uniform, but the continuity of the crystal grain was low bec
ause of the defects. In addition, variation in contrast was observed i
n the crystals, however, no obvious variation in chemical composition
was found in this region of varying contrast. Therefore, the contrast
variation is considered to be attributed to the dislocation. Such a di
slocation was found to be occurred in the direction of the (20 (1) und
er bar (0) under bar) plane in many instances. The defects in the SBT
film were also confirmed by the TEM observation.