DIFFERENT STRUCTURES FOR 2 VERY SIMILAR 2-BENZOYLPYRIDINE AZACYCLOTHIOSEMICARBAZONES

Authors
VALDESMARTINEZ J HERNANDEZORTEGA S WEST DX IVES JS BAIN GA
Citation
J. Valdesmartinez et al., DIFFERENT STRUCTURES FOR 2 VERY SIMILAR 2-BENZOYLPYRIDINE AZACYCLOTHIOSEMICARBAZONES, Zeitschrift fur Kristallographie, 213(4), 1998, pp. 246-248
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Zeitschrift fur Kristallographie → ACNP
ISSN journal
00442968
Volume
213
Issue
4
Year of publication
1998
Pages
246 - 248
Database
ISI
SICI code
0044-2968(1998)213:4<246:DSF2VS>2.0.ZU;2-D
Abstract
2-Benzoylpyridine piperidinyl- and hexamethyleneiminylthiosemicarbazon es, HBzpip and HBzhexim, respectively, crystallize in a hydrogen bonde d Z isomeric conformation with respect to the C7-N2 bond. The intramol ecular hydrogen bond is between N3-H...N1, but the S atom is E to the azomethine nitrogen, N2, for HBzpip and Z for HBzhexim. HBzpip is the second ZE isomer known, but the first that does not have a formal hydr ogen bond to N2.