K2MCL6 (M = PT, IR) - LOCATION OF THE SILENT MODES AND FORCEFIELDS

Authors
PARKER SF FORSYTH JB
Citation
Sf. Parker et Jb. Forsyth, K2MCL6 (M = PT, IR) - LOCATION OF THE SILENT MODES AND FORCEFIELDS, Journal of the Chemical Society. Faraday transactions, 94(8), 1998, pp. 1111-1114
Citations number
24
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
94
Issue
8
Year of publication
1998
Pages
1111 - 1114
Database
ISI
SICI code
0956-5000(1998)94:8<1111:K(=PI->2.0.ZU;2-6
Abstract
The use of inelastic neutron scattering spectroscopy has enabled all t he internal and external modes of K2MCl6 (M = Pt, Ir) to be observed a nd assigned for the first time. Based on the results, a reliable, empi rical forcefield has been developed. Comparison with forcefields in th e literature show that previously they all suffered from using an inco mplete set of frequencies.