PHYSICAL-PROPERTIES AND STRUCTURES OF PSEUDOHALOGENOCOPPER(II) COMPLEXES WITH PHENANTHROLINE

Authors
MASLEJOVA A POTOCNAK I SIMA J KABESOVA M
Citation
A. Maslejova et al., PHYSICAL-PROPERTIES AND STRUCTURES OF PSEUDOHALOGENOCOPPER(II) COMPLEXES WITH PHENANTHROLINE, Journal of coordination chemistry, 43(1), 1998, pp. 41-51
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
43
Issue
1
Year of publication
1998
Pages
41 - 51
Database
ISI
SICI code
0095-8972(1998)43:1<41:PASOPC>2.0.ZU;2-O
Abstract
Electronic, IR and EPR spectra of eight Cu(II) complexes with trigonal -bipyramidal, tetragonal-bipyramidal and tetragonal-pyramidal coordina tion polyhedra containing phenanthroline and pseudohalogenide ligands were examined and their interrelationships with molecular and crystal structures evaluated. Along with the usual trigonal-bipyramidal enviro nment of Cu(II), tetragonal symmetry for four complexes was observed. The origin of this tetragonal symmetry is connected with intermolecula r interaction of phenanthroline with pseudohalide ligands.