REDUCTIVE CLEAVAGE OF 2,2,2-TRICHLOROETHYL ESTERS WITH SODIUM TELLURIDE

Authors
BLAY G CARDONA L GARCIA B GARCIA CL PEDRO JR
Citation
G. Blay et al., REDUCTIVE CLEAVAGE OF 2,2,2-TRICHLOROETHYL ESTERS WITH SODIUM TELLURIDE, Synthetic communications, 28(8), 1998, pp. 1405-1414
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
8
Year of publication
1998
Pages
1405 - 1414
Database
ISI
SICI code
0039-7911(1998)28:8<1405:RCO2EW>2.0.ZU;2-S
Abstract
Carboxylic acids are regenerated from their 2,2,2,-trichloroethyl este rs by treatment with sodium telluride in dimethylformamide in smooth c onditions and with good yields. The reaction conditions are compatible with other functional and protective groups such as methyl ester, ace tate or tert-butyldimethylsilyl ethers.