Computer simulation is a useful tool for the design and synthesis of n
ew process flowsheets and/or the analysis of existing processes which
can lead to improvements in conditions of operation and savings in ene
rgy. Relationships between physico- chemical properties and separation
process principles have been employed to identify a set of the most f
easible separation techniques for a given separation task. A screening
procedure is employed to generate the alternatives that are most like
ly to be efficient in terms of energy utilization and environmental im
pact. For separation processes requiring the use of a mass separating
agent (solvent), the choice of the solvent is critical in terms of sep
aration as well as in utilization of energy and environmental impact.
Use of the appropriate solvent is highlighted through a case study whi
ch involves the recovery of cyclohexane. Aspects of design and synthes
is are highlighted with respect to separation feasibility, energy util
ization and environmental impact. The results from the case study show
that savings in energy between 13% and 32% can be achieved while incr
easing the recovery by 7 % for a cyclohexane product of 99.9% (mole) p
urity.