The origin of photoconductivity within diamond is briefly reviewed. Se
veral applications Cor thin film diamond formed by chemical vapour dep
osition (CVD) could be realised if the extrinsic photoconductive respo
nse could be controlled, including the fabrication of deep UV photodet
ectors which are ''blind'' to visible light. It is possible to reduce
the extrinsic photoconductive response otherwise apparent in CVD films
by a combination of careful device design and well chosen post fabric
ation gaseous treatments; the nature of the treatments used and how th
ey may be affecting defects within the diamond are discussed. Highly s
ensitive deep UV photodetectors call be produced in this manner, exhib
iting external quantum efficiencies of greater than 500%. (C) 1997 Els
evier Science S.A.