Mpl. Werts et al., CHEMICAL CONTRAST ON A MICROPHASE-SEPARATED BLOCK-COPOLYMER SURFACE OBSERVED BY SCANNING FORCE MICROSCOPY, Advanced materials, 10(6), 1998, pp. 452
Friction force imaging of microphase-separated copolymers using scanni
ng force microscopy (SFM) is demonstrated to be a viable technique for
distinguishing between polymer blocks. The Figure is a friction force
image of a cross section of a film of a polystyrene-poly(2-vinylpyrid
ine) (PS-PVP) star copolymer measured with a COOH-modified tip, reveal
ing the morphology of the copolymer.