J. Spatz et al., CONTROLLED MINERALIZATION AND ASSEMBLY OF HYDROLYSIS-BASED NANOPARTICLES IN ORGANIC-SOLVENTS COMBINING POLYMER MICELLES AND MICROWAVE TECHNIQUES, Advanced materials, 10(6), 1998, pp. 473
Controlled formation of nanoparticles in inverse diblock copolymer mic
elles by hydrolysis of titanium alkoxide precursors is described. Coag
ulation of the resulting TiO2-loaded micelles occurs on casting if the
sample is prepared by conventional heating, allowing strings of TiO2
particles to form (see Figure). It is demonstrated that this can be pr
evented by microwave heating.