TRIS(TETRAPHENYLIMIDODIPHOSPHINATO)GADOLI NIUM, GD(TPIP)(3), A NEW RELAXATION REAGENT FOR STRUCTURAL STUDIES OF ACYCLIC AND POLYCYCLIC CARBOXYLIC-ACIDS AND PHENOLS

Authors
BARKAOUI L CHARROUF M RAGER MN DENISE B PLATZER N RUDLER H
Citation
L. Barkaoui et al., TRIS(TETRAPHENYLIMIDODIPHOSPHINATO)GADOLI NIUM, GD(TPIP)(3), A NEW RELAXATION REAGENT FOR STRUCTURAL STUDIES OF ACYCLIC AND POLYCYCLIC CARBOXYLIC-ACIDS AND PHENOLS, Bulletin de la Societe chimique de France, 134(2), 1997, pp. 167-175
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
134
Issue
2
Year of publication
1997
Pages
167 - 175
Database
ISI
SICI code
0037-8968(1997)134:2<167:TNGANR>2.0.ZU;2-K
Abstract
Tris(tetraphenylimidodiphosphinato)gadolinium, Gd(tpip)(3), is a relax ation reagent that gives labile complexes in solution with carboxylic acids and phenols. A study of the longitudinal relaxation of the carbo ns in a substrate in the presence of this reagent allows a simple anal ysis of the spectrum. Information on relative configurations and confo rmation can be obtained.