Objectives. To investigate the daily fluoride release of two glass ion
omers (Ketac-Fil and ChemFil Superior) and two compomers (Compoglass a
nd Dyract Restorative) over 6 months. Methods. A pilot study evaluated
the rime taken for sample solutions to equilibrate to establish an ap
propriate time period for sample solution storage between fluoride ion
measurements. In the main study storage water replacement and fluorid
e ion determination was made daily using a specific ion electrode, TIS
AB buffer and standard solutions for calibration. Results. Equilibrati
on of fluoride concentration in aqueous solution occurred in under 48
h for all materials. Total fluoride released (mu g mm(-2)) after 6 mon
ths by Ketac-Fil (30.6, s.d. 4.9) was significantly greater than ChemF
il Superior (12.7, s.d. 2.5), Compoglass (10.4, s.d. 1.0) end Dyract R
estorative (7.7, s.d. 1.7) (P<0.05). Daily fluoride release at 24 h an
d 10 days was significantly higher for the glass ionomers than the com
pomers (P<0.05). After 40 days the daily fluoride release (mu g mm(-2)
) from ChemFil Superior (0.05, s.d. 0.01) was not significantly differ
ent from Compoglass (0.04, s.d. 0.01) and Dyract Restorative (0.03, s.
d. 0.00) (P>0.05). Daily fluoride release from Ketac-Fil remains signi
ficantly higher than the compomers at 3 and 6 months (P<0.05). Conclus
ions. Specimens stored in water equilibrate rapidly, suggesting the ra
te at which storage water is changed may alter the relative fluoride r
elease rates of materials. This important fact is often overlooked. Fl
uoride release from the glass ionomers is initially higher than for th
e compomers. Fluoride release from glass ionomers falls rapidly to app
roach levels released by compomers. Compomers produce no initial burst
of fluoride and levels of release remain relatively constant. (C) 199
8 Elsevier Science Ltd. All rights reserved.